Carbon dating calculation
Much of the information presented in this section is based upon the Stuiver and Polach (1977) paper "Discussion: Reporting of C14 data". 1890 wood was chosen as the radiocarbon standard because it was growing prior to the fossil fuel effects of the industrial revolution.
The resulting radiocarbon combines with atmospheric oxygen to form radioactive carbon dioxide, which is incorporated into plants by photosynthesis; animals then acquire in a sample from a dead plant or animal such as a piece of wood or a fragment of bone provides information that can be used to calculate when the animal or plant died.Because of the fossil fuel effect, this is not actually the activity level of wood from 1950; the activity would have been somewhat lower.The fossil fuel effect was eliminated from the standard value by measuring wood from 1890, and using the radioactive decay equations to determine what the activity would have been at the year of growth.Organic materials, which require the most processing, are limited to younger ages by their corresponding process blank.Due to counting and measurement errors for the blanks and samples, statistical errors are higher for very old samples.However, limiting ages or "backgrounds" are also determined by process blanks which correspond to the method used to extract the carbon from the sample.
» NOSAMS General Statement of C from contamination introduced during chemical preparation, collection or handling.
Although one can simply measure older samples for longer times, there are practical limits to the minimum sample activity that can be measured.
At the present time, for a 1 milligram sample of graphite, this limiting age is about ten half-lives, or 60,000 years, if set only by the sample size.
The Oxalic acid standard was made from a crop of 1955 sugar beet. The isotopic ratio of HOx I is -19.3 per mille with respect to (wrt) the PBD standard belemnite (Mann, 1983). T designation SRM 4990 C) was made from a crop of 1977 French beet molasses.
The Oxalic acid standard which was developed is no longer commercially available. In the early 1980's, a group of 12 laboratories measured the ratios of the two standards.
This is addressed by defining the standard to be 0.95 times the activity of HOx I.